Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate]

Poly[[aquatris(μ-benzene-1,4-dicarboxylato)tricobalt(II)] methanol monosolvate monohydrate]

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The asymmetric unit of the title compound, {[Co3(C8H4O4)3(H2O)]·CH3OH·H2O}n, consists of four crystallographically independent Co cations, four benzene-1,4-dicarboxylate (bdc) anions, two water and one methanol solvent molecule.Two merrick backcountry wet cat food of the Co cations and two of the bdc anions are located on centres of inversion, whereas all other atoms are located in general positions.In the crystal, two Co atoms are only fourfold coordinated by three O atoms from three bdc ligands and by one O atom from one coordinated water molecule, while click here a third Co atom is coordinated by four O atoms from four bdc ligands within a strongly distorted tetrahedral geometry.The other two Co cations are octahedrally coordinated by six O atoms from six bdc anions.

The Co cations are linked by the bdc anions into a three-dimensional framework.From this arrangement, cavities are formed in which additional methanol and water molecules are embedded.